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Issue 10, 2008
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Synthesis of imidazolidin-2-one-4-carboxylate and of (tetrahydro)pyrimidin-2-one-5-carboxylatevia an efficient modification of the Hofmann rearrangement

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Abstract

A mild and efficient methodology for the rearrangement of protected asparagine and protected glutamine is reported; good results are obtained with a wide selection of protecting groups.

Graphical abstract: Synthesis of imidazolidin-2-one-4-carboxylate and of (tetrahydro)pyrimidin-2-one-5-carboxylatevia an efficient modification of the Hofmann rearrangement

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Article information


Submitted
01 Feb 2008
Accepted
05 Mar 2008
First published
07 Apr 2008

Org. Biomol. Chem., 2008,6, 1849-1852
Article type
Paper

Synthesis of imidazolidin-2-one-4-carboxylate and of (tetrahydro)pyrimidin-2-one-5-carboxylatevia an efficient modification of the Hofmann rearrangement

G. Angelici, S. Contaldi, S. Lynn Green and C. Tomasini, Org. Biomol. Chem., 2008, 6, 1849
DOI: 10.1039/B801909F

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