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Issue 9, 2008
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Immobilization of platinum(II) and palladium(II) complexes on metal oxides by sol–gel processing and surface modification using bifunctional phosphine–phosphonate esters

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Abstract

The bifunctional phosphine–phosphonate ester derivatives Ph2P(CH2)3P(O)(OSiMe3)2 (L), (cis-Cl2Pt[Ph2P(CH2)3P(O)(OSiMe3)2]2 (1), trans-Cl2Pd[Ph2P(C6H4)P(O)(OSiMe3)2]2 (2) and trans-Cl2Pd[Ph2P(C6H4)P(O)(OEt)2]2 (3) were used to immobilize platinum(II) and palladium(II) complexes on metal oxide supports by three different routes: sol–gel incorporation of L in TiO2 or ZrO2 matrices followed by complexation with PtCl2(PhCN)2, direct sol–gel immobilization of 1 and 2, surface modification of TiO2nanoparticles with 2 and 3. The hybrid solids were characterized by solid-state 31P MAS NMR spectroscopy, surface area measurements and chemical analysis; the advantages and disadvantages of the different routes were discussed. This study demonstrates that phosphonic esters can provide a valuable alternative to phosphonic acids for the preparation of functional organic–inorganic hybrids based on metal oxides.

Graphical abstract: Immobilization of platinum(ii) and palladium(ii) complexes on metal oxides by sol–gel processing and surface modification using bifunctional phosphine–phosphonate esters

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Publication details

The article was received on 07 Jan 2008, accepted on 04 Apr 2008 and first published on 07 May 2008


Article type: Paper
DOI: 10.1039/B800250A
New J. Chem., 2008,32, 1519-1525

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    Immobilization of platinum(II) and palladium(II) complexes on metal oxides by sol–gel processing and surface modification using bifunctional phosphine–phosphonate esters

    G. Guerrero, P. H. Mutin, E. Framery and A. Vioux, New J. Chem., 2008, 32, 1519
    DOI: 10.1039/B800250A

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