Jump to main content
Jump to site search

Issue 4, 2008
Previous Article Next Article

Modulation and binding properties of extended glycoluril molecular clips

Author affiliations

Abstract

A glycoluril clip (1) provides a deep cavity for binding of guest molecules. Guest species interact preferentially viahydrogen bonding or ion–lone pair interactions. Complexation-induced conformational modulation of the cavity wall distance was observed. At higher guest–host ratios, inclusion compounds with organic guest molecules are obtained. The X-ray crystallographic structure of 1·(NH4PF6)·3CHCl3·2CH3OH shows formation of a network of clips connected via polar and non-polar interactions.

Graphical abstract: Modulation and binding properties of extended glycoluril molecular clips

Back to tab navigation

Supplementary files

Publication details

The article was received on 03 Oct 2007, accepted on 10 Dec 2007 and first published on 08 Jan 2008


Article type: Paper
DOI: 10.1039/B715208F
New J. Chem., 2008,32, 643-651

  •   Request permissions

    Modulation and binding properties of extended glycoluril molecular clips

    P. Polavarapu, H. Melander, V. Langer, A. Gogoll and H. Grennberg, New J. Chem., 2008, 32, 643
    DOI: 10.1039/B715208F

Search articles by author

Spotlight

Advertisements