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Issue 46, 2008
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An unusual anionic copper(I) cyanide 3D framework encapsulating a cationic copper(II) complex as a guest

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Abstract

From the reaction of CuICN with conc-NH4OH, a host–guest type 3D network complex 1, {[CuII(NH3)4(H2O)](H2O)@[CuI3(CN)5]}n was isolated and characterised. A unique cationic complex guest [CuII(NH3)4(H2O)]2+ is encapsulated in the anionic host cage [CuI3(CN)5]2−.

Graphical abstract: An unusual anionic copper(i) cyanide 3D framework encapsulating a cationic copper(ii) complex as a guest

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Publication details

The article was received on 22 Aug 2008, accepted on 30 Sep 2008 and first published on 21 Oct 2008


Article type: Communication
DOI: 10.1039/B814646B
Dalton Trans., 2008, 6521-6523

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    An unusual anionic copper(I) cyanide 3D framework encapsulating a cationic copper(II) complex as a guest

    K. Park, S. Lee, Y. Kang, S. Moon and S. S. Lee, Dalton Trans., 2008, 6521
    DOI: 10.1039/B814646B

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