Issue 46, 2008
From the journal:

Dalton Transactions

An unusual anionic copper(i) cyanide 3D framework encapsulating a cationic copper(ii) complex as a guest†

Ki-Min Park,*a   Sanjina Lee,a   Youngjin Kang,b   Suk-Hee Moonc  and  Shim Sung Leea  

* Corresponding authors

a Research Institute of Natural Science and Department of Chemistry (BK21), Gyeongsang National University, Jinju, South Korea
E-mail: kmpark@gnu.ac.kr
Fax: +82-55-756-0512
Tel: +82-55-751-6592

b Division of Science Education, Kangwon National University, Chuncheon, South Korea

c Subdivision of Food Science, Kyungnam College of Information and Technology, Busan, South Korea

Abstract

From the reaction of CuICN with conc-NH4OH, a host–guest type 3D network complex 1, {[CuII(NH3)4(H2O)](H2O)@[CuI3(CN)5]}n was isolated and characterised. A unique cationic complex guest [CuII(NH3)4(H2O)]2+ is encapsulated in the anionic host cage [CuI3(CN)5]2−.

Graphical abstract: An unusual anionic copper(i) cyanide 3D framework encapsulating a cationic copper(ii) complex as a guest

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Article information

DOI
https://doi.org/10.1039/B814646B
Article type
Communication
Submitted
22 Aug 2008
Accepted
30 Sep 2008
First published
21 Oct 2008

Dalton Trans., 2008, 6521-6523

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An unusual anionic copper(I) cyanide 3D framework encapsulating a cationic copper(II) complex as a guest

K. Park, S. Lee, Y. Kang, S. Moon and S. S. Lee, Dalton Trans., 2008, 6521 DOI: 10.1039/B814646B

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