Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 43, 2008
Previous Article Next Article

Syntheses and molecular structures of some saturated N-heterocyclic plumbylenes

Author affiliations

Abstract

Cyclic diamino plumbylenes derived from saturated heterocycles are obtained from deprotonation of diamines and subsequent reaction with PbCl2, or by reaction of a suitable diamine with Pb[N(SiMe3)2]2. Single crystal X-ray studies have been used to probe the solid state structures of a range of these complexes and have shown the fine balance between monomer and dimer formation which is related to the bulk of the organic group attached to the nitrogen atoms. Dimerisation is also shown to effect structural changes within the core of the heterocyclic plumbylene.

Graphical abstract: Syntheses and molecular structures of some saturated N-heterocyclic plumbylenes

Back to tab navigation

Supplementary files

Article information


Submitted
22 May 2008
Accepted
22 Jul 2008
First published
23 Sep 2008

Dalton Trans., 2008, 6055-6059
Article type
Paper

Syntheses and molecular structures of some saturated N-heterocyclic plumbylenes

J. P. H. Charmant, M. F. Haddow, F. E. Hahn, D. Heitmann, R. Fröhlich, S. M. Mansell, C. A. Russell and D. F. Wass, Dalton Trans., 2008, 6055
DOI: 10.1039/B808717B

Social activity

Search articles by author

Spotlight

Advertisements