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Issue 31, 2008
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A unique six-membered chelated iridium complex

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Abstract

The reaction of 2-(3-methylbiphenyl-2-yl)pyridine with IrCl3·nH2O in the presence of water incorporates a tightly bonded CO at the iridium center; in the subsequent reaction with picolinic acid a complex revealing an unusual CH activation of a methyl group is formed.

Graphical abstract: A unique six-membered chelated iridium complex

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Article information


Submitted
06 May 2008
Accepted
06 Jun 2008
First published
16 Jun 2008

Dalton Trans., 2008, 4095-4098
Article type
Communication

A unique six-membered chelated iridium complex

S. Ammermann, C. Daniliuc, P. G. Jones, W. du Mont, W. Kowalsky and H. Johannes, Dalton Trans., 2008, 4095
DOI: 10.1039/B807735P

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