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Issue 21, 2008
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Electronic modification of an aminotroponiminate zinc complex leading to an increased reactivity in the hydroamination of alkenes

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Abstract

The electronically modified zinc complex 5-phenylsulfanyl-N-isopropyl-2-(isopropylamino)troponiminate zinc methyl, [{PhS-ATI(iPr)2}ZnMe], was synthesized. It showed an increased reactivity in the intramolecular hydroamination reaction of non-activated alkenes compared to a previously-reported, non-substituted complex.

Graphical abstract: Electronic modification of an aminotroponiminate zinc complex leading to an increased reactivity in the hydroamination of alkenes

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Publication details

The article was received on 11 Dec 2007, accepted on 04 Mar 2008 and first published on 04 Apr 2008


Article type: Paper
DOI: 10.1039/B719120K
Dalton Trans., 2008, 2844-2848

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    Electronic modification of an aminotroponiminate zinc complex leading to an increased reactivity in the hydroamination of alkenes

    M. Dochnahl, K. Löhnwitz, J. Pissarek, P. W. Roesky and S. Blechert, Dalton Trans., 2008, 2844
    DOI: 10.1039/B719120K

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