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Issue 46, 2008
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Activation of molecular oxygen by S-radicals: experimental and computational studies on a novel oxidation of alkynes to α-diketones

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Abstract

Thiylperoxyl radicals 14 are the suggested reactive key-intermediates in the oxidation of bis-aromatic alkynes to α-diketones using molecular oxygen “activated” by thiyl radicals.

Graphical abstract: Activation of molecular oxygen by S-radicals: experimental and computational studies on a novel oxidation of alkynes to α-diketones

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Supplementary files

Article information


Submitted
03 Sep 2008
Accepted
30 Sep 2008
First published
16 Oct 2008

Chem. Commun., 2008, 6239-6241
Article type
Communication

Activation of molecular oxygen by S-radicals: experimental and computational studies on a novel oxidation of alkynes to α-diketones

K. J. Tan and U. Wille, Chem. Commun., 2008, 6239
DOI: 10.1039/B815358B

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