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Issue 46, 2008
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Enhancement of H2 adsorption in Li+-exchanged co-ordination framework materials

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Abstract

H2 adsorption in (Me2NH2)[In(L)] is enhanced by exchange of Me2NH2+ for Li+ cations; the Li+-exchanged material displays a lower isosteric heat for H2 adsorption than the parent material, indicating that the increase in H2 capacity is due to an increase in the accessible pore volume on cation exchange, while the lower adsorption enthalpy is consistent with increased pore size.

Graphical abstract: Enhancement of H2 adsorption in Li+-exchanged co-ordination framework materials

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Publication details

The article was received on 14 Aug 2008, accepted on 25 Sep 2008 and first published on 14 Oct 2008


Article type: Communication
DOI: 10.1039/B814155J
Chem. Commun., 2008, 6108-6110

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    Enhancement of H2 adsorption in Li+-exchanged co-ordination framework materials

    S. Yang, X. Lin, A. J. Blake, K. M. Thomas, P. Hubberstey, N. R. Champness and M. Schröder, Chem. Commun., 2008, 6108
    DOI: 10.1039/B814155J

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