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A quantitative structure–reactivity relationship in decarboxylative Claisen rearrangement reactions of allylic tosylmalonate esters†
Abstract
First-order rate constants have been determined for the decarboxylative
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Supplementary files
- Experimental procedures and analytical data for the synthesis and characterisation of 1, 3, and synthetic intermediates; tabulated integral data vs. time for rearrangement reactions of 1a–f PDF (597K)
- nmr spectra ( 1H, 13C and where appropriate 19F) for 1, 3, and synthetic intermediates PDF (3827K)
- Summarised kinetic data and first-order plots PDF (969K)
Article information
- Article type
- Communication
- Submitted
- 18 Jul 2008
- Accepted
- 29 Sep 2008
- First published
- 14 Oct 2008
Chem. Commun., 2008, 6054-6056
Permissions
A quantitative structure–reactivity relationship in decarboxylative Claisen rearrangement reactions of allylic tosylmalonate esters
D. Craig and N. K. Slavov, Chem. Commun., 2008, 6054 DOI: 10.1039/B812306C
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