Issue 45, 2008

Cooperativity between π–π and H-bonding interactions–a supramolecular complex formed by C60 and exTTF

Abstract

A highly stable supramolecular complex from C60 and exTTF (Ka ≈ 106 M−1) has been achieved by means of π–π and H-bonding interactions; experimental evidence reveals the formation of a radical–ion pair (τ = 9.3 ps) upon photoexcitation.

Graphical abstract: Cooperativity between π–π and H-bonding interactions–a supramolecular complex formed by C60 and exTTF

Supplementary files

Article information

Article type
Communication
Submitted
03 Jul 2008
Accepted
18 Sep 2008
First published
14 Oct 2008

Chem. Commun., 2008, 5993-5995

Cooperativity between π–π and H-bonding interactions–a supramolecular complex formed by C60 and exTTF

J. Santos, B. Grimm, B. M. Illescas, D. M. Guldi and N. Martín, Chem. Commun., 2008, 5993 DOI: 10.1039/B811358K

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