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Issue 42, 2008
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Orthogonal or simultaneous use of disulfide and hydrazone exchange in dynamic covalent chemistry in aqueous solution

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Abstract

Hydrazone and disulfide exchange have been combined in a single system, but can be addressed independently: by adjusting the pH of the solution from acidic to mildly basic it is possible to switch from exclusively hydrazone exchange to exclusively disulfide exchange, while at intermediate pH both reactions occur simultaneously.

Graphical abstract: Orthogonal or simultaneous use of disulfide and hydrazone exchange in dynamic covalent chemistry in aqueous solution

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Article information


Submitted
22 May 2008
Accepted
16 Jul 2008
First published
11 Sep 2008

Chem. Commun., 2008, 5301-5303
Article type
Communication

Orthogonal or simultaneous use of disulfide and hydrazone exchange in dynamic covalent chemistry in aqueous solution

Z. Rodriguez-Docampo and S. Otto, Chem. Commun., 2008, 5301
DOI: 10.1039/B808725C

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