Issue 23, 2008
From the journal:

Chemical Communications

Structurally-defined potassium-mediated regioselective zincation of amino- and alkoxy-substituted pyridines†

Ben Conway,a   David V. Graham,a   Eva Hevia,a   Alan R. Kennedy,a   Jan Kletta  and  Robert E. Mulvey*a  

* Corresponding authors

a WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK
E-mail: r.e.mulvey@strath.ac.uk

Abstract

The new synergic base [PMDETA·K(TMP)(Et)Zn(Et)] selectively zincates 4-(dimethylamino)pyridine at the 2-position and 4-methoxypyridine at the 3-position, to afford bimetallic potassium pyridylzinc complexes each displaying a novel, but remarkably different, structure.

Graphical abstract: Structurally-defined potassium-mediated regioselective zincation of amino- and alkoxy-substituted pyridines

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Article information

DOI
https://doi.org/10.1039/B805606D
Article type
Communication
Submitted
03 Apr 2008
Accepted
23 Apr 2008
First published
16 May 2008

Chem. Commun., 2008, 2638-2640

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Structurally-defined potassium-mediated regioselective zincation of amino- and alkoxy-substituted pyridines

B. Conway, D. V. Graham, E. Hevia, A. R. Kennedy, J. Klett and R. E. Mulvey, Chem. Commun., 2008, 2638 DOI: 10.1039/B805606D

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