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Issue 20, 2008
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Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant

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Abstract

Palladium catalysed intramolecular guanidine transfer to alkenes can be accomplished with copper chloride as the oxidant to give bicyclic guanidines with complete selectivity and in high yields.

Graphical abstract: Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant

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Supplementary files

Article information


Submitted
19 Dec 2007
Accepted
11 Feb 2008
First published
14 Mar 2008

Chem. Commun., 2008, 2334-2336
Article type
Communication

Direct synthesis of bicyclic guanidines through unprecedented palladium(II) catalysed diamination with copper chloride as oxidant

C. H. Hövelmann, J. Streuff, L. Brelot and K. Muñiz, Chem. Commun., 2008, 2334
DOI: 10.1039/B719479J

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