Issue 20, 2008
From the journal:

Chemical Communications

Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant†‡

Claas H. Hövelmann,a   Jan Streuff,a   Lydia Brelota  and  Kilian Muñiz*a  

* Corresponding authors

a Institut de Chimie, UMR 7177, Université Louis Pasteur, 4 rue Blaise Pascal, Strasbourg Cedex, France
E-mail: muniz@chimie.u-strasbg.fr

Abstract

Palladium catalysed intramolecular guanidine transfer to alkenes can be accomplished with copper chloride as the oxidant to give bicyclic guanidines with complete selectivity and in high yields.

Graphical abstract: Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant

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Article information

DOI
https://doi.org/10.1039/B719479J
Article type
Communication
Submitted
19 Dec 2007
Accepted
11 Feb 2008
First published
14 Mar 2008

Chem. Commun., 2008, 2334-2336

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Direct synthesis of bicyclic guanidines through unprecedented palladium(II) catalysed diamination with copper chloride as oxidant

C. H. Hövelmann, J. Streuff, L. Brelot and K. Muñiz, Chem. Commun., 2008, 2334 DOI: 10.1039/B719479J

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