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Issue 9, 2008
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Intramolecularcation–π interactions control the conformation of nonrestricted (phenylalkyl)pyridines

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Abstract

NOEsy and fluorescence spectroscopy reveal that conversion of conformationally flexible (phenylalkyl)pyridines into their corresponding N-methyl-pyridinium iodides results in intramolecular π-stacking.

Graphical abstract: Intramolecular cation–π interactions control the conformation of nonrestricted (phenylalkyl)pyridines

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Article information


Submitted
01 Nov 2007
Accepted
06 Dec 2007
First published
08 Jan 2008

Chem. Commun., 2008, 1082-1084
Article type
Communication

Intramolecular cation–π interactions control the conformation of nonrestricted (phenylalkyl)pyridines

I. Richter, J. Minari, P. Axe, J. P. Lowe, T. D. James, K. Sakurai, S. D. Bull and J. S. Fossey, Chem. Commun., 2008, 1082
DOI: 10.1039/B716937J

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