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Issue 1, 2008
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Assembling metals and clusters around an octaphosphine ligand based on N-substituted bis(diphenylphosphanyl)amines: structural characterization of dendrimer-like Co12 and Co16 branched clusters

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Abstract

A polypodal ligand based on an aromatic ring decorated by four dppa-type diphosphine moieties has been used to prepare Pt(II) complexes and to assemble four tricobalt or tetracobalt carbonyl clusters, leading to centrosymmetric Co12 and Co16 «clusters of clusters» which were characterized by X-ray diffraction.

Graphical abstract: Assembling metals and clusters around an octaphosphine ligand based on N-substituted bis(diphenylphosphanyl)amines: structural characterization of dendrimer-like Co12 and Co16 branched clusters

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Submitted
04 Sep 2007
Accepted
24 Sep 2007
First published
19 Oct 2007

Chem. Commun., 2008, 64-66
Article type
Communication

Assembling metals and clusters around an octaphosphine ligand based on N-substituted bis(diphenylphosphanyl)amines: structural characterization of dendrimer-like Co12 and Co16 branched clusters

M. Rodriguez-Zubiri, V. Gallo, J. Rosé, R. Welter and P. Braunstein, Chem. Commun., 2008, 64
DOI: 10.1039/B713540H

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