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Issue 1, 2008
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Assembling metals and clusters around an octaphosphine ligand based on N-substituted bis(diphenylphosphanyl)amines: structural characterization of dendrimer-like Co12 and Co16 branched clusters

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Abstract

A polypodal ligand based on an aromatic ring decorated by four dppa-type diphosphine moieties has been used to prepare Pt(II) complexes and to assemble four tricobalt or tetracobalt carbonyl clusters, leading to centrosymmetric Co12 and Co16 «clusters of clusters» which were characterized by X-ray diffraction.

Graphical abstract: Assembling metals and clusters around an octaphosphine ligand based on N-substituted bis(diphenylphosphanyl)amines: structural characterization of dendrimer-like Co12 and Co16 branched clusters

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Publication details

The article was received on 04 Sep 2007, accepted on 24 Sep 2007 and first published on 19 Oct 2007


Article type: Communication
DOI: 10.1039/B713540H
Chem. Commun., 2008, 64-66

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    Assembling metals and clusters around an octaphosphine ligand based on N-substituted bis(diphenylphosphanyl)amines: structural characterization of dendrimer-like Co12 and Co16 branched clusters

    M. Rodriguez-Zubiri, V. Gallo, J. Rosé, R. Welter and P. Braunstein, Chem. Commun., 2008, 64
    DOI: 10.1039/B713540H

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