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Issue 36, 2008
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Chemoenzymatic synthesis of GDP-azidodeoxymannoses: non-radioactive probes for mannosyltransferase activity

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Abstract

GDP-2-, 3-, 4- or 6-azidomannoses can be successfully prepared from the corresponding azidomannose-1-phosphates and GTP using the enzyme GDP-Mannosepyrophosphorylase (GDP-ManPP) from Salmonella enterica and may serve as useful probes for mannosyltransferase activity.

Graphical abstract: Chemoenzymatic synthesis of GDP-azidodeoxymannoses: non-radioactive probes for mannosyltransferase activity

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Supplementary files

Article information


Submitted
25 Apr 2008
Accepted
02 Jun 2008
First published
18 Jul 2008

Chem. Commun., 2008, 4321-4323
Article type
Communication

Chemoenzymatic synthesis of GDP-azidodeoxymannoses: non-radioactive probes for mannosyltransferase activity

S. Marchesan and D. Macmillan, Chem. Commun., 2008, 4321
DOI: 10.1039/B807016D

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