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Issue 13, 2008
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Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(iii)–CF3 reagents

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Abstract

A direct, mild and efficient trifluoromethylation of primary and secondary phosphines is achieved with easily accessible, cheap hypervalent iodine compounds acting as electrophilic CF3-transfer reagents.

Graphical abstract: Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(iii)–CF3 reagents

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Publication details

The article was received on 25 Jan 2008, accepted on 20 Feb 2008 and first published on 03 Mar 2008


Article type: Communication
DOI: 10.1039/B801424H
Chem. Commun., 2008, 1575-1577

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    Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(III)–CF3 reagents

    P. Eisenberger, I. Kieltsch, N. Armanino and A. Togni, Chem. Commun., 2008, 1575
    DOI: 10.1039/B801424H

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