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Issue 11, 2008
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Nickeladihydrofuran. Key intermediate for nickel-catalyzed reaction of alkyne and aldehyde

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Abstract

The formation of a nickeladihydrofuran by oxidative cyclization of an alkyne and an aldehyde with nickel(0) has been demonstrated; the transformation of the nickeladihydrofuran into an enone by decomposition, a lactone by carbonylation and an allylic alcohol by treatment with ZnMe2 suggests that nickeladihydrofuran is an important key intermediate in a variety of catalytic reactions.

Graphical abstract: Nickeladihydrofuran. Key intermediate for nickel-catalyzed reaction of alkyne and aldehyde

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Publication details

The article was received on 12 Nov 2007, accepted on 20 Dec 2007 and first published on 21 Jan 2008


Article type: Communication
DOI: 10.1039/B717261C
Chem. Commun., 2008, 1347-1349

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    Nickeladihydrofuran. Key intermediate for nickel-catalyzed reaction of alkyne and aldehyde

    S. Ogoshi, T. Arai, M. Ohashi and H. Kurosawa, Chem. Commun., 2008, 1347
    DOI: 10.1039/B717261C

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