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Issue 6, 2008
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High yielding alkylations of unactivated sp3 and sp2 centres with alkyl-9-BBN reagents using an NHC-based catalyst: Pd-PEPPSI-IPr

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Abstract

High yielding, room temperature cross couplings of unactivated alkyl bromides and aryl bromides/chlorides with alkyl-9-BBN reagents has been achieved using an NHC-based catalyst (Pd-PEPPSI-IPr) via a general, functional-group tolerant and easily implemented protocol.

Graphical abstract: High yielding alkylations of unactivated sp3 and sp2 centres with alkyl-9-BBN reagents using an NHC-based catalyst: Pd-PEPPSI-IPr

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Article information


Submitted
01 Oct 2007
Accepted
23 Nov 2007
First published
07 Dec 2007

Chem. Commun., 2008, 735-737
Article type
Communication

High yielding alkylations of unactivated sp3 and sp2 centres with alkyl-9-BBN reagents using an NHC-based catalyst: Pd-PEPPSI-IPr

C. Valente, S. Baglione, D. Candito, C. J. O'Brien and M. G. Organ, Chem. Commun., 2008, 735
DOI: 10.1039/B715081D

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