Reactions of phosphate and phosphorothiolate diesters with nucleophiles: comparison of transition state structures
Abstract
A series of methyl aryl phosphorothiolate esters (SP) were synthesized and their reactions with
* Corresponding authors
a Department of Biochemistry and Molecular Biology, Department of Chemistry, Howard Hughes Medical Institute, The University of Chicago, 929 E 57th St., Chicago, Illinois 60637, USA
b General Anesthesiology, Cleveland Clinic, 9500 Euclid Avenue, Cleveland, OH 44195, USA
c 5329 W. Greenwood, Skokie, IL 60077, USA
d Laboratory of RNA Molecular Biology, Rockefeller University, 1230 York Avenue, Box 186, New York, NY 10021, USA
A series of methyl aryl phosphorothiolate esters (SP) were synthesized and their reactions with
J. Ye, C. D. Barth, P. S. R. Anjaneyulu, T. Tuschl and J. A. Piccirilli, Org. Biomol. Chem., 2007, 5, 2491 DOI: 10.1039/B707205H
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