Issue 14, 2007
From the journal:

Organic & Biomolecular Chemistry

Diastereo- and enantioselective synthesis of α,β-epoxyketones using aqueous NaOCl in conjunction with dihydrocinchonidine derived phase-transfer catalysis at room temperature. Scope and limitations

Barry Lygo,*a   Stuart D. Gardiner,a   Michael C. McLeoda  and  Daniel C. M. Toa  

* Corresponding authors

a School of Chemistry, University of Nottingham, Nottingham, UK

Abstract

In this paper we present studies into the scope and limitations of asymmetric PTC epoxidation of enones and the oxidation–epoxidation of allylic alcohols using aqueous NaOCl in conjunction with a dihydrocinchonidine derived quaternary ammoniumsaltcatalyst.

Graphical abstract: Diastereo- and enantioselective synthesis of α,β-epoxyketones using aqueous NaOCl in conjunction with dihydrocinchonidine derived phase-transfer catalysis at room temperature. Scope and limitations

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Article information

DOI
https://doi.org/10.1039/B706546A
Article type
Paper
Submitted
30 Apr 2007
Accepted
18 May 2007
First published
13 Jun 2007

Org. Biomol. Chem., 2007,5, 2283-2290

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Diastereo- and enantioselective synthesis of α,β-epoxyketones using aqueous NaOCl in conjunction with dihydrocinchonidine derived phase-transfer catalysis at room temperature. Scope and limitations

B. Lygo, S. D. Gardiner, M. C. McLeod and D. C. M. To, Org. Biomol. Chem., 2007, 5, 2283 DOI: 10.1039/B706546A

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