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Abstract | Cited by

A series of symmetric and non-symmetric bis(oxazoline) ligands were applied in the Nozaki–Hiyama–Kishi methallylation of a range of aromatic and aliphatic aldehydes. A non-symmetrical ligand with tert-butyl/benzyl-substituted oxazolines provided the highest enantioselectivity of 99.5% for the methallylation of benzaldehyde.

Graphical abstract: The application of bis(oxazoline) ligands in the catalytic enantioselective methallylation of aldehydes

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