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Issue 11, 2007
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Supramolecular assembly based on p-sulfonatothiacalix[6]arene with sodium and water molecules†

Manabu Yamada,a   Yoshihiko Kondo,a   Kazuhiko Akimoto,b   Chizuko Kabutoc  and  Fumio Hamada*a  
Author affiliations

* Corresponding authors

a Department of Materials-process & Applied Chemistry for Environments, Faculty of Engineering and Resource Science, Akita University, Akita 010-8502, Japan
E-mail: hamada@ipc.akita-u.ac.jp
Fax: +81 18 837 0404
Tel: +81 18 889 2440

b Electronic Materials Research Laboratories, Nissan chemical Industries, Ltd, 635 Sasakura, Fuchu-Machi, Toyama 939-2792, Japan

c Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan

Abstract

A water-soluble p-sulfonatothiacalix[6]arene (1) has been prepared in high yield and the inclusion complex with hydrated sodium cations and water has been investigated by X-ray crystal analysis. Host 1 formed a complex with two hydrated sodium cations with ten and sixteen water molecules.

Graphical abstract: Supramolecular assembly based on p-sulfonatothiacalix[6]arene with sodium and water molecules

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Article information

https://doi.org/10.1039/B706891C
Submitted
08 May 2007
Accepted
28 Aug 2007
First published
04 Sep 2007
New J. Chem., 2007,31, 1874-1877
Article type
Letter
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Supramolecular assembly based on p-sulfonatothiacalix[6]arene with sodium and water molecules

M. Yamada, Y. Kondo, K. Akimoto, C. Kabuto and F. Hamada, New J. Chem., 2007, 31, 1874
DOI: 10.1039/B706891C

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