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Issue 41, 2007
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Hexanuclear [Ni6L12] metallacrown framework consisting of NiS4 square-planar and NiS5 square-pyramidal building blocks

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Abstract

The hexanuclear [Ni6L12] (2) wheel-type cluster adopts an unusual structural motif whereby four NiS4 square-planar and two NiS5 square-pyramidal units are conjoined by edge sharing; the NiS5 units resemble the Ni centre of the inactive state in the [NiFe] hydrogenase.

Graphical abstract: Hexanuclear [Ni6L12] metallacrown framework consisting of NiS4 square-planar and NiS5 square-pyramidal building blocks

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Article information


Submitted
05 Sep 2007
Accepted
12 Sep 2007
First published
19 Sep 2007

Dalton Trans., 2007, 4641-4643
Article type
Communication

Hexanuclear [Ni6L12] metallacrown framework consisting of NiS4 square-planar and NiS5 square-pyramidal building blocks

R. Angamuthu, H. Kooijman, M. Lutz, A. L. Spek and E. Bouwman, Dalton Trans., 2007, 4641
DOI: 10.1039/B713668B

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