Asymmetric hydroamination of non-activated carbon–carbon multiple bonds

Abstract

The catalysed enantioselective formation of carbon–nitrogen bonds by the hydroamination reaction is reviewed. All examples deal with substrates containing non-activated carbon–carbon multiple bonds which are transformed either via intramolecular or intermolecular reactions. Structurally different complexes already provided nitrogen containing compounds/heterocycles with high enantioselectivities.