Issue 28, 2007
From the journal:

Dalton Transactions

Synthesis and characterisation of zinc gallyl complexes: First structural elucidations of Zn–Ga bonds†‡

Cameron Jones,*a   Richard P. Roseab  and  Andreas Staschab  

* Corresponding authors

a School of Chemistry, Monash University, PO Box 23, Melbourne, Victoria, Australia

b School of Chemistry, Main Building, Cardiff University, Cardiff, UK

Abstract

Reactions of the anionic gallium(I) heterocycle, [:Ga{[N(Ar)C(H)]2}]− (Ar = C6H3Pri2-2,6), with two N,N-chelated zinc chloride complexes have yielded the compounds, [{Pri2NC[N(Ar)]2}ZnGa{[N(Ar)C(H)]2}] and [(tmeda)Zn{Ga{[N(Ar)C(H)]2}}2] which contain the first crystallographically characterised Zn–Ga bonds.

Graphical abstract: Synthesis and characterisation of zinc gallyl complexes: First structural elucidations of Zn–Ga bonds

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Article information

DOI
https://doi.org/10.1039/B706402K
Article type
Communication
Submitted
27 Apr 2007
Accepted
30 May 2007
First published
14 Jun 2007

Dalton Trans., 2007, 2997-2999

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Synthesis and characterisation of zinc gallyl complexes: First structural elucidations of Zn–Ga bonds

C. Jones, R. P. Rose and A. Stasch, Dalton Trans., 2007, 2997 DOI: 10.1039/B706402K

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