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A tin sulfonate–oxidehydroxide tetracation with two different sulfonate bindings, an electrostatic and a monohapto covalent one, and a tin sulfonate–oxidehydroxide monocation with two other kinds of sulfonate bindings, an electrostatic and a dihapto bridging one are described here.

Graphical abstract: Sn3 and Sn10 sulfonate–oxide–hydroxide clusters with two different sulfonate binding modes

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