Issue 19, 2007
From the journal:

Dalton Transactions

Rigidity-modulated conformation control: a strategy for incorporating flexible building motifs into metallacycles†

Malaichamy Sathiyendiran,a   Che-Hao Chang,a   Chuan-Hung Chuang,a   Tzuoo-Tsair Luo,a   Yuh-Sheng Wena  and  Kuang-Lieh Lu*a  

* Corresponding authors

a Institute of chemistry, Academia Sinica, Taipei, Taiwan
E-mail: lu@chem.sinica.edu.tw
Fax: +886-2-27831237
Tel: +886-2-27898518

Abstract

A rigidity-modulated strategy for the conformational control of a flexible motif in the self-assembly of metallacycles is described; the span of the rigid ligand directs the conformation of the flexible motif by fixing the M⋯M separation, thereby dictating the structure of the metallacycles.

Graphical abstract: Rigidity-modulated conformation control: a strategy for incorporating flexible building motifs into metallacycles

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Article information

DOI
https://doi.org/10.1039/B702810E
Article type
Communication
Submitted
23 Feb 2007
Accepted
19 Mar 2007
First published
27 Mar 2007

Dalton Trans., 2007, 1872-1874

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Rigidity-modulated conformation control: a strategy for incorporating flexible building motifs into metallacycles

M. Sathiyendiran, C. Chang, C. Chuang, T. Luo, Y. Wen and K. Lu, Dalton Trans., 2007, 1872 DOI: 10.1039/B702810E

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