Issue 18, 2007
From the journal:

Dalton Transactions

[Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a well characterised transition metal dichloroethane complex†

Gemma L. Moxham,a   Simon K. Brayshawa  and  Andrew S. Weller*a  

* Corresponding authors

a Department of Chemistry, University of Bath, Bath, UK
E-mail: a.s.weller@bath.ac.uk

Abstract

Reaction of [Ir(PPh3)2(COD)][BArF4] with H2 in dichloroethane solution results in [Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4], which has been fully characterised by X-ray crystallography, NMR spectroscopy and ESI-MS. Its activity towards alkene hydrogenation has been compared with analogous CH2Cl2 complexes.

Graphical abstract: [Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a well characterised transition metal dichloroethane complex

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Article information

DOI
https://doi.org/10.1039/B702399E
Article type
Communication
Submitted
15 Feb 2007
Accepted
13 Mar 2007
First published
26 Mar 2007

Dalton Trans., 2007, 1759-1761

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[Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a well characterised transition metal dichloroethane complex

G. L. Moxham, S. K. Brayshaw and A. S. Weller, Dalton Trans., 2007, 1759 DOI: 10.1039/B702399E

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