Issue 10, 2007
From the journal:

CrystEngComm

Predictable and unpredictable reactions between 4,4′-dipyridyldisulfide and phosphonodithioato/dithiophosphato NiII complexes: novel coordination polymers and the unique example of 4,4′-dipyridyltrisulfide

M. Carla Aragoni,*a   Massimiliano Arca,a   Miriam Crespo,a   Francesco A. Devillanova,a   Michael B. Hursthouse,b   Susanne L. Huth,b   Francesco Isaia,a   Vito Lippolisa  and  Gaetano Verania  

* Corresponding authors

a Dipartimento di Chimica Inorganica ed Analitica, Università degli Studi di Cagliari, S.S. 554 bivio per Sestu, Monserrato-Cagliari, Italy
E-mail: aragoni@unica.it
Fax: +39 0706754456
Tel: +39070 6754491

b School of Chemistry, University of Southampton, Highfield, Southampton, UK

Abstract

The reactions between dpds and the phosphonodithioato and dithiophosphato NiII complexes [Ni(MeOpdt)2] (1), [Ni(EtOpdt)2] (2), and [Ni((EtO)2PS2)2] (3) yielded the novel coordination polymers (1·dpds)∞, (2·dpts)∞, and (3·dps)∞, featuring three different spacers ensuing from in situ chemical rearrangement of the starting dpds reagent (dpds, 4,4′-dipyridyldisulfide; dps, 4,4′-dipyridylmonosulfide; dpts, 4,4′-dipyridyltrisulfide).

Graphical abstract: Predictable and unpredictable reactions between 4,4′-dipyridyldisulfide and phosphonodithioato/dithiophosphato NiII complexes: novel coordination polymers and the unique example of 4,4′-dipyridyltrisulfide

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Article information

DOI
https://doi.org/10.1039/B708972D
Article type
Communication
Submitted
18 Jun 2007
Accepted
01 Aug 2007
First published
16 Aug 2007

CrystEngComm, 2007,9, 873-878

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Predictable and unpredictable reactions between 4,4′-dipyridyldisulfide and phosphonodithioato/dithiophosphato NiII complexes: novel coordination polymers and the unique example of 4,4′-dipyridyltrisulfide

M. C. Aragoni, M. Arca, M. Crespo, F. A. Devillanova, M. B. Hursthouse, S. L. Huth, F. Isaia, V. Lippolis and G. Verani, CrystEngComm, 2007, 9, 873 DOI: 10.1039/B708972D

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