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Issue 10, 2007
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Predictable and unpredictable reactions between 4,4′-dipyridyldisulfide and phosphonodithioato/dithiophosphato NiII complexes: novel coordination polymers and the unique example of 4,4′-dipyridyltrisulfide

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Abstract

The reactions between dpds and the phosphonodithioato and dithiophosphato NiII complexes [Ni(MeOpdt)2] (1), [Ni(EtOpdt)2] (2), and [Ni((EtO)2PS2)2] (3) yielded the novel coordination polymers (1·dpds), (2·dpts)∞, and (3·dps), featuring three different spacers ensuing from in situ chemical rearrangement of the starting dpds reagent (dpds, 4,4′-dipyridyldisulfide; dps, 4,4′-dipyridylmonosulfide; dpts, 4,4′-dipyridyltrisulfide).

Graphical abstract: Predictable and unpredictable reactions between 4,4′-dipyridyldisulfide and phosphonodithioato/dithiophosphato NiII complexes: novel coordination polymers and the unique example of 4,4′-dipyridyltrisulfide

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Article information


Submitted
18 Jun 2007
Accepted
01 Aug 2007
First published
16 Aug 2007

CrystEngComm, 2007,9, 873-878
Article type
Communication

Predictable and unpredictable reactions between 4,4′-dipyridyldisulfide and phosphonodithioato/dithiophosphato NiII complexes: novel coordination polymers and the unique example of 4,4′-dipyridyltrisulfide

M. C. Aragoni, M. Arca, M. Crespo, F. A. Devillanova, M. B. Hursthouse, S. L. Huth, F. Isaia, V. Lippolis and G. Verani, CrystEngComm, 2007, 9, 873
DOI: 10.1039/B708972D

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