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Abstract | Cited by

We describe a new interpenetrated pillared-grid structure based on Cu(II) paddle-wheels, 4,4′-biphenyldicarboxylate and 4,4′-bipyridine, with 51% non-framework volume and which retains the same structure on desolvation.

Graphical abstract: A pillared-grid MOF with large pores based on the Cu2(O2CR)4 paddle-wheel

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