Issue 45, 2007
From the journal:

Chemical Communications

Samarium(ii) iodide-mediated intramolecular pinacol coupling reactions with cyclopropyl ketones†

Sarah L. Foster,a   Sandeep Handa,*a   Michael Kraffta  and  David Rowlinga  

* Corresponding authors

a Department of Chemistry, University of Leicester, Leicester, UK
E-mail: s.handa@le.ac.uk
Fax: +44 (0)116 252 3789
Tel: +44 (0)116 252 2128

Abstract

The first reported intramolecular pinacol coupling of cyclopropyl ketones has been achieved, demonstrating that cyclisation competes favourably with ring-opening of the cyclopropyl ketyl radical.

Graphical abstract: Samarium(ii) iodide-mediated intramolecular pinacol coupling reactions with cyclopropyl ketones

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Article information

DOI
https://doi.org/10.1039/B712542A
Article type
Communication
Submitted
15 Aug 2007
Accepted
28 Aug 2007
First published
05 Sep 2007

Chem. Commun., 2007, 4791-4793

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Samarium(II) iodide-mediated intramolecular pinacol coupling reactions with cyclopropyl ketones

S. L. Foster, S. Handa, M. Krafft and D. Rowling, Chem. Commun., 2007, 4791 DOI: 10.1039/B712542A

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