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Issue 46, 2007
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Base free lithium-organoaluminate and the gallium congener: potential precursors to heterometallic assemblies

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Abstract

The first examples of base free lithium-organoaluminate and the corresponding gallium compound [LM(Me)OLi]3 (M = Al (3), Ga (4); L = HC{C(Me)N-2,6-iPr2C6H3}2) have been prepared by the reaction of Li[N(SiMe3)2] with the corresponding metal hydroxides LM(Me)OH (M = Al (1), Ga(2)); the oxygen atom in the M–O–Li fragment exists as oxide ion and is involved in the central Li3O3 six-membered ring formation.

Graphical abstract: Base free lithium-organoaluminate and the gallium congener: potential precursors to heterometallic assemblies

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Publication details

The article was received on 09 Aug 2007, accepted on 11 Oct 2007 and first published on 29 Oct 2007


Article type: Communication
DOI: 10.1039/B712240C
Citation: Chem. Commun., 2007,0, 4934-4936

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    Base free lithium-organoaluminate and the gallium congener: potential precursors to heterometallic assemblies

    S. Singh, J. Chai, A. Pal, V. Jancik, H. W. Roesky and R. Herbst-Irmer, Chem. Commun., 2007, 0, 4934
    DOI: 10.1039/B712240C

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