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Issue 46, 2007
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Catalytically efficient palladium nanoparticles stabilized by “click” ferrocenyl dendrimers

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Abstract

1,2,3-Ferrocenyl triazole ligands generated by click reactions in dendrimers bind Pd(OAc)2 with a systematic one-to-one stoichiometry as monitored by titration using the ferrocenyl redox sensor attached to the triazole ring, and the dendritic PdII complexes formed are best reduced by methanol to form palladium nanoparticles of designed types and sizes that show excellent efficiency and selectivity in olefin hydrogenation.

Graphical abstract: Catalytically efficient palladium nanoparticles stabilized by “click” ferrocenyl dendrimers

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Article information


Submitted
17 Jul 2007
Accepted
06 Sep 2007
First published
20 Sep 2007

Chem. Commun., 2007, 4946-4948
Article type
Communication

Catalytically efficient palladium nanoparticles stabilized by “click” ferrocenyl dendrimers

C. Ornelas, L. Salmon, J. Ruiz Aranzaes and D. Astruc, Chem. Commun., 2007, 4946
DOI: 10.1039/B710925C

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