Issue 41, 2007

Functionalization of silicon surfaces with catalytically active Pd complexes and application to the aerobic oxidation of benzylic alcohols

Abstract

A single-crystal silicon surface was modified with a bisoxazoline–Pd molecular layer and utilized as a highly efficient (catalyst turnover number up to 780 000, 110 °C, 72 h) and recyclable catalyst in the aerobic oxidation of benzylic alcohols.

Graphical abstract: Functionalization of silicon surfaces with catalytically active Pd complexes and application to the aerobic oxidation of benzylic alcohols

Supplementary files

Article information

Article type
Communication
Submitted
16 Jul 2007
Accepted
26 Jul 2007
First published
10 Aug 2007

Chem. Commun., 2007, 4280-4282

Functionalization of silicon surfaces with catalytically active Pd complexes and application to the aerobic oxidation of benzylic alcohols

K. Hara, S. Tayama, H. Kano, T. Masuda, S. Takakusagi, T. Kondo, K. Uosaki and M. Sawamura, Chem. Commun., 2007, 4280 DOI: 10.1039/B710820F

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