Issue 47, 2007
From the journal:

Chemical Communications

Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct†

Patrick Spies,a   Gerhard Erker,*a   Gerald Kehr,a   Klaus Bergander,a   Roland Fröhlich,‡a   Stefan Grimme§a  and  Douglas W. Stephanb  

* Corresponding authors

a Organisch-Chemisches Institut, Universität Münster, Corrensstraße 40, Germany
E-mail: erker@uni-muenster.de
Fax: +49 251-83 36503

b Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario, Canada

Abstract

A four-membered cyclic intramolecular phosphane–borane adduct activates dihydrogen to yield the respective ethylene-bridged zwitterionic phosphonium–hydridoborate system, which reduces benzaldehyde.

Graphical abstract: Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct

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Article information

DOI
https://doi.org/10.1039/B710475H
Article type
Communication
Submitted
10 Jul 2007
Accepted
13 Sep 2007
First published
02 Oct 2007

Chem. Commun., 2007, 5072-5074

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Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct

P. Spies, G. Erker, G. Kehr, K. Bergander, R. Fröhlich, S. Grimme and D. W. Stephan, Chem. Commun., 2007, 5072 DOI: 10.1039/B710475H

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