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Issue 40, 2007
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Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene

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Abstract

A structurally well-defined THF-free cationic half-sandwich scandium aminobenzyl complex serves as a novel catalyst for the first copolymerization of 1-hexene with dicyclopentadiene to give the random copolymers with a wide range of 1-hexene contents (32–70 mol%) unavailable previously.

Graphical abstract: Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene

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Publication details

The article was received on 05 Jun 2007, accepted on 13 Jul 2007 and first published on 02 Aug 2007


Article type: Communication
DOI: 10.1039/B708534F
Citation: Chem. Commun., 2007,0, 4137-4139

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    Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene

    X. Li, M. Nishiura, K. Mori, T. Mashiko and Z. Hou, Chem. Commun., 2007, 0, 4137
    DOI: 10.1039/B708534F

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