Issue 35, 2007
From the journal:

Chemical Communications

Sequential C–F activation and borylation of fluoropyridines via intermediate Rh(i) fluoropyridyl complexes: a multinuclear NMR investigation†

Richard J. Lindup,a   Todd B. Marder,b   Robin N. Perutz*a  and  Adrian C. Whitwooda  

* Corresponding authors

a Department of Chemistry, University of York, York, UK
E-mail: rnp1@york.ac.uk
Fax: +44 (0) 1904 43 2516
Tel: +44 (0) 1904 43 2549

b Department of Chemistry, Durham University, Durham, UK
E-mail: todd.marder@durham.ac.uk
Fax: +44 (0) 191 384 4737
Tel: +44 (0) 191 334 2037

Abstract

The C–F bond activation of fluoropyridines by [Rh(SiPh3)(PMe3)3] afforded Rh(I) fluoropyridyl complexes of the type [Rh(ArF)(PMe3)3] with concomitant formation of fluorotriphenylsilane; subsequent treatment with bis-catecholatodiboron yielded fac-[Rh(Bcat)3(PMe3)3] and the free fluoropyridyl boronate esters (ArFBcat).

Graphical abstract: Sequential C–F activation and borylation of fluoropyridines via intermediate Rh(i) fluoropyridyl complexes: a multinuclear NMR investigation

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Article information

DOI
https://doi.org/10.1039/B707840D
Article type
Communication
Submitted
23 May 2007
Accepted
05 Jun 2007
First published
26 Jun 2007

Chem. Commun., 2007, 3664-3666

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Sequential C–F activation and borylation of fluoropyridines via intermediate Rh(I) fluoropyridyl complexes: a multinuclear NMR investigation

R. J. Lindup, T. B. Marder, R. N. Perutz and A. C. Whitwood, Chem. Commun., 2007, 3664 DOI: 10.1039/B707840D

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