Issue 44, 2007

Cα,Cortho-Dimetalated phosphazene complexes

Abstract

The first Cα,Cortho dilithium complex of a phosphazene has been synthesized as a single stereoisomer and has been structurally characterized in solution; the complex is monomeric, with the dianion acting as an N–Cortho and O–Cα chelate. Transmetallation with Me3SnCl and PhHgCl afforded the first Cα,Cortho homo- and hetero-bimetallic phosphazene complexes, which contain a desymmetrised Ph2PN moiety.

Graphical abstract: Cα,Cortho-Dimetalated phosphazene complexes

Supplementary files

Article information

Article type
Communication
Submitted
15 May 2007
Accepted
23 Jul 2007
First published
28 Aug 2007

Chem. Commun., 2007, 4674-4676

Cα,Cortho-Dimetalated phosphazene complexes

J. G. López, I. Fernández, M. S. Ruiz and F. L. Ortiz, Chem. Commun., 2007, 4674 DOI: 10.1039/B707320H

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