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Issue 37, 2007
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µ-Acetylide and µ-alkenylidene ligands in “click” triazole syntheses

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Abstract

In a computational investigation, dinuclear and tetranuclear copper acetylide complexes display both superior stability and higher reactivity in the CuAAC reaction than do mononuclear complexes due to favored dicopper(I,III) µ-alkenylidene fragments, instead of ring strain in a Cu[double bond, length as m-dash]C[double bond, length as m-dash]C intermediate.

Graphical abstract: µ-Acetylide and µ-alkenylidene ligands in “click” triazole syntheses

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Publication details

The article was received on 08 May 2007, accepted on 28 Jun 2007 and first published on 12 Jul 2007


Article type: Communication
DOI: 10.1039/B706926J
Chem. Commun., 2007, 3868-3870

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    µ-Acetylide and µ-alkenylidene ligands in “click” triazole syntheses

    B. F. Straub, Chem. Commun., 2007, 3868
    DOI: 10.1039/B706926J

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