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Issue 36, 2007
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Unprecedented (3,4)-connected metal–organic frameworks (MOFs) with 3-fold interpenetration and considerable solvent-accessible void space

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Abstract

Via solvothermal synthesis, the self-assembly of CuCl2, 1,3,5-benzenetricarboxylic acid, and N,N′-bis(4-pyridylformamide)-1,4-benzene in DMF generated a novel coordination polymer containing an unprecedented (3,4)-connected network; 3-fold interpenetration and considerable solvent-accessible cavities occupied by reversible guest water molecules were also observed.

Graphical abstract: Unprecedented (3,4)-connected metal–organic frameworks (MOFs) with 3-fold interpenetration and considerable solvent-accessible void space

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Publication details

The article was received on 24 Apr 2007, accepted on 15 Jun 2007 and first published on 03 Jul 2007


Article type: Communication
DOI: 10.1039/B706177C
Chem. Commun., 2007, 3744-3746

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    Unprecedented (3,4)-connected metal–organic frameworks (MOFs) with 3-fold interpenetration and considerable solvent-accessible void space

    F. Luo, J. Zheng and S. R. Batten, Chem. Commun., 2007, 3744
    DOI: 10.1039/B706177C

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