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Issue 31, 2007
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Rhodium(i)-catalysed conjugate phosphination of cyclic α,β-unsaturated ketones with silylphosphines as masked phosphinides

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Abstract

Nucleophile-activation of the phosphorus(III)–silicon linkage in silylphosphines generates a nucleophilic phosphorus(III) equivalent thereby allowing for a rhodium-catalysed conjugate phosphination of β-substituted α,β-unsaturated acceptors.

Graphical abstract: Rhodium(i)-catalysed conjugate phosphination of cyclic α,β-unsaturated ketones with silylphosphines as masked phosphinides

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Article information


Submitted
24 Apr 2007
Accepted
22 May 2007
First published
11 Jun 2007

Chem. Commun., 2007, 3300-3302
Article type
Communication

Rhodium(I)-catalysed conjugate phosphination of cyclic α,β-unsaturated ketones with silylphosphines as masked phosphinides

V. T. Trepohl and M. Oestreich, Chem. Commun., 2007, 3300
DOI: 10.1039/B706137D

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