Issue 27, 2007
From the journal:

Chemical Communications

Synthesis and catalytic properties of MIL-100(Fe), an iron(iii) carboxylate with large pores†

Patricia Horcajada,a   Suzy Surblé,a   Christian Serre,*a   Do-Young Hong,b   You-Kyong Seo,b   Jong-San Chang,b   Jean-Marc Grenèche,c   Irene Margiolakid  and  Gérard Féreya  

* Corresponding authors

a Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin-en-Yvelines, 45 Avenue des Etats-Unis, Versailles Cédex, France
E-mail: serre@chimie.uvsq.fr
Fax: 00 33 1 39 25 43 58
Tel: 00 33 1 39 25 43 05 ;

b Catalysis Centre for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT), Jang-dong 100, Yuseong-Gu, Daejon, South Korea

c Laboratoire de Physique de L'Etat Condensé, UMR CNRS 6087, Université du Maine, Le Mans Cedex 9, France

d ESRF, rue J. Horowitz, Grenoble Cedex, France

Abstract

The large-pore iron(III) carboxylate MIL-100(Fe) with a zeotype architecture has been isolated under hydrothermal conditions, its structure solved from synchrotron X-ray powder diffraction data, while Friedel–Crafts benzylation catalytic tests indicate a high activity and selectivity for MIL-100(Fe).

Graphical abstract: Synthesis and catalytic properties of MIL-100(Fe), an iron(iii) carboxylate with large pores

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Article information

DOI
https://doi.org/10.1039/B704325B
Article type
Communication
Submitted
21 Mar 2007
Accepted
01 May 2007
First published
15 May 2007

Chem. Commun., 2007, 2820-2822

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Synthesis and catalytic properties of MIL-100(Fe), an iron(III) carboxylate with large pores

P. Horcajada, S. Surblé, C. Serre, D. Hong, Y. Seo, J. Chang, J. Grenèche, I. Margiolaki and G. Férey, Chem. Commun., 2007, 2820 DOI: 10.1039/B704325B

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