Selective modification of β-cyclodextrin: an unexpected tandem reaction enables the cross-linking of C2A and C2B via a sulfur atom

Makoto Fukudome; Kazuki Yoshikawa; Kazutaka Koga; De-Qi Yuan; Kahee Fujita

doi:10.1039/B703943C

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Selective modification of β-cyclodextrin: an unexpected tandem reaction enables the cross-linking of C2^A and C2^B via a sulfur atom

Makoto Fukudome,^a Kazuki Yoshikawa,^a Kazutaka Koga,^b De-Qi Yuan*^a and Kahee Fujita*^a

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* Corresponding authors

^a Department of Molecular Medicinal Sciences, Graduate School of Biomedical Sciences, Nagasaki University, Bunkyo-machi 1-14, Japan
E-mail: fujita@nagasaki-u.ac.jp, deqiyuan@nagasaki-u.ac.jp

^b Nihon Pharmaceutical University, Kita-adachi, Japan

Abstract

2^A,3^A-Alloepithio-2^B-sulfonyl-β-cyclodextrin undergoes a tandem reaction to generate an unprecedented C2^A–S–C2^B-bridged glucosyl-3^A,6^A-anhydroglucoside segment.

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Article information

DOI: https://doi.org/10.1039/B703943C
Article type: Communication
Submitted: 15 Mar 2007
Accepted: 03 May 2007
First published: 22 May 2007

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Chem. Commun., 2007, 3157-3159

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Selective modification of β-cyclodextrin: an unexpected tandem reaction enables the cross-linking of C2^A and C2^B via a sulfur atom

M. Fukudome, K. Yoshikawa, K. Koga, D. Yuan and K. Fujita, Chem. Commun., 2007, 3157 DOI: 10.1039/B703943C

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Chemical Communications

Selective modification of β-cyclodextrin: an unexpected tandem reaction enables the cross-linking of C2^A and C2^B via a sulfur atom

Abstract

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Selective modification of β-cyclodextrin: an unexpected tandem reaction enables the cross-linking of C2^A and C2^B via a sulfur atom

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