Issue 24, 2007
From the journal:

Chemical Communications

Strained azetidinium ylides: new reagents for epoxidation†

Audrey Alex,a   Bénédicte Larmanjat,a   Jérôme Marrot,a   François Coutya  and  Olivier David*a  

* Corresponding authors

a Institut Lavoisier, Université de Versailles St Quentin-en-Yvelines,, 45 avenue des Etats-Unis, Versailles
E-mail: odavid@chimie.uvsq.fr
Fax: 33 1 3925 4452
Tel: 33 1 3925 4455

Abstract

Azetidinium ylides effected facile epoxidation of various carbonyl compounds furnishing tri or tetrasubstituted epoxides that were unattainable via classical ammonium ylide chemistry; the produced trisubstituted oxiranes gave rise to a remarkable cascade of reactions leading to some original pyrrolidin-3-ones.

Graphical abstract: Strained azetidinium ylides: new reagents for epoxidation

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Article information

DOI
https://doi.org/10.1039/B701848G
Article type
Communication
Submitted
06 Feb 2007
Accepted
08 Mar 2007
First published
22 Mar 2007

Chem. Commun., 2007, 2500-2502

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Strained azetidinium ylides: new reagents for epoxidation

A. Alex, B. Larmanjat, J. Marrot, F. Couty and O. David, Chem. Commun., 2007, 2500 DOI: 10.1039/B701848G

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