Issue 23, 2007
From the journal:

Chemical Communications

Insertion of arynes into carbon–halogen σ-bonds: regioselective acylation of aromatic rings†

Hiroto Yoshida,*a   Yasuhiro Mimura,a   Joji Ohshitaa  and  Atsutaka Kunai*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima, Japan
E-mail: yhiroto@hiroshima-u.ac.jp
Fax: +81-82-424-5494
Tel: +81-82-424-7724

Abstract

Arynes were found to insert into carbon–halogen σ-bonds of various acid halides, enabling acyl and halogen moieties to be introduced simultaneously into adjacent positions of aromatic rings.

Graphical abstract: Insertion of arynes into carbon–halogen σ-bonds: regioselective acylation of aromatic rings

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Article information

DOI
https://doi.org/10.1039/B701581J
Article type
Communication
Submitted
01 Feb 2007
Accepted
21 Feb 2007
First published
09 Mar 2007

Chem. Commun., 2007, 2405-2407

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Insertion of arynes into carbon–halogen σ-bonds: regioselective acylation of aromatic rings

H. Yoshida, Y. Mimura, J. Ohshita and A. Kunai, Chem. Commun., 2007, 2405 DOI: 10.1039/B701581J

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