Issue 20, 2007
From the journal:

Chemical Communications

Lithium dimer formation in the Li-conducting garnets Li5+xBaxLa3−xTa2O12 (0 < x ≤ 1.6)†

Michael P. O'Callaghana  and  Edmund J. Cussen*a  

* Corresponding authors

a WestCHEM, Department of Pure and Applied Chemistry, Thomas Graham Building, University of Strathclyde, 295 Cathedral Street, Glasgow, Scotland
E-mail: Edmund.Cussen@Strath.ac.uk
Fax: +44 141 548 4822
Tel: +44 141 548 2797

Abstract

The garnet system Li5+xBaxLa3−xTa2O12 shows an unprecedented Li+ content (x ≤ 1.6) and short Li–Li distances of ca 2.44 Å between majority occupied sites suggesting that the high Li+ mobility requires a complex cooperative mechanism.

Graphical abstract: Lithium dimer formation in the Li-conducting garnets Li5+xBaxLa3−xTa2O12 (0 < x ≤ 1.6)

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Article information

DOI
https://doi.org/10.1039/B700369B
Article type
Communication
Submitted
11 Jan 2007
Accepted
14 Mar 2007
First published
03 Apr 2007

Chem. Commun., 2007, 2048-2050

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Lithium dimer formation in the Li-conducting garnets Li5+xBaxLa3−xTa2O12 (0 < x ≤ 1.6)

M. P. O'Callaghan and E. J. Cussen, Chem. Commun., 2007, 2048 DOI: 10.1039/B700369B

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