Linkage isomerism in a face-centered cubic Cu6Cr8(CN)24 cluster with an S = 15 ground state†
Abstract
Access to the new complex [TpCr(CN)3]− enables isolation of two metastable linkage isomers of a face-centered cubic cluster, [Tp8(H2O)6Cu6Cr8(CN)24]4+, both exhibiting an S = 15 ground state.