Gallium(i)–alkaline earth metal donor–acceptor bonds†
Abstract
Compounds with a gallium–alkaline earth metal bond, [(η5-C5Me5)2Ca–Ga(η5-C5Me5)], [(η5-C5Me5)2(THF)Sr–Ga(η5-C5Me5)], and [(η5-C5Me5)2Ba–{Ga(η5-C5Me5)}2], were prepared.
* Corresponding authors
a
Institut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstr. 34-36, 14195 Berlin, Germany
E-mail:
roesky@chemie.fu-berlin.de
Fax: +49 (0)30-83 85 24 40
b
Institut für Physikalische Chemie, Lehrstuhl für Theoretische Chemie, Universität Karlsruhe (TH), Germany
E-mail:
reinhart.ahlrichs@chemie.uni-karlsruhe.de
Fax: +49(0)721 608 7225
c
Institute of Inorganic Chemistry, Siberian Division of RAS, Acad. Lavrentyev str. 3, Novosibirsk 630090, Russia
E-mail:
konch@che.nsk.su
Fax: +7 3833 309489
Compounds with a gallium–alkaline earth metal bond, [(η5-C5Me5)2Ca–Ga(η5-C5Me5)], [(η5-C5Me5)2(THF)Sr–Ga(η5-C5Me5)], and [(η5-C5Me5)2Ba–{Ga(η5-C5Me5)}2], were prepared.
M. Wiecko, P. W. Roesky, P. Nava, R. Ahlrichs and S. N. Konchenko, Chem. Commun., 2007, 927 DOI: 10.1039/B614165J
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